Connect with us

Space & Physics

What brought carbon to Earth

This marks the first time a complex form of carbon essential for life on Earth has been observed outside the solar system. To learn more about the significance of this discovery, EdPublica interviewed the researchers behind the study– Gabi Wenzel, Ilsa Cooke, and Brett McGuire, who shared their insights on the implications of pyrene’s presence in space and its potential impact on our understanding of star and planet formation

Dipin Damodharan

Published

on

The findings suggest pyrene may have been the source of much of the carbon in our solar system. “It’s an almost unbelievable sink of carbon,” says Brett McGuire, right, standing with lead author of the study Gabi Wenzel. Credits: Photo: Bryce Vickmark

A team led by researchers at MIT has detected pyrene, a complex carbon-containing molecule, in a distant interstellar cloud. This finding opens new avenues for understanding the chemical origins of our solar system. Pyrene, a type of polycyclic aromatic hydrocarbon (PAH), was found in a molecular cloud similar to the one from which our solar system formed.

This marks the first time a complex form of carbon essential for life on Earth has been observed outside the solar system. Its discovery sheds light on how the compounds necessary for life could originate in space. The team detected pyrene in
a star-forming region known as the Taurus Molecular Cloud, located 430 light-years away, making it one of the closest such clouds to Earth.

This discovery also aligns with recent findings from the asteroid Ryugu, suggesting that pyrene may have played a key role in the carbon composition of the early solar system. To learn more about the significance of this discovery, EdPublica interviewed the researchers behind the study– Gabi Wenzel, Ilsa Cooke, and Brett McGuire, who shared their insights on the implications of pyrene’s presence in space and its potential impact on our understanding of star and planet formation. Brett McGuire is an assistant professor of chemistry at MIT, Ilsa Cooke is an assistant professor of chemistry at the University of British Columbia, and Gabi Wenzel is a postdoctoral researcher in McGuire’s group at MIT.

Below, the team responds to questions from EdPublica Editor Dipin Damodharan about this unexpected and exciting discovery.

‘Pyrene could be a major source of carbon in our solar system’

Q: How does the discovery of pyrene in TMC-1 enhance our understanding of the chemical inventory that contributed to the formation of our solar system?

Gabi Wenzel:

Stars much like our own sun are born from dense molecular clouds. The discovery of pyrene in a molecular cloud called TMC-1, one that might be very similar to our sun’s natal cloud and which will go on to form a star of its own, significantly enhances our understanding of the chemical inventory that contributed to the formation of our own solar system. As a polycyclic aromatic hydrocarbon (PAH), pyrene is one of the most complex organic molecules found in early molecular clouds, suggesting that the building blocks of organic matter were available in the environments where stars and their orbiting (exo)planets form.

“One of the big questions in star and planet formation is: How much of the chemical inventory from that early molecular cloud is inherited and forms the base components of the solar system? What we’re looking at is the start and the end, and they’re showing the same thing.” McGuire says. Credits:Photo: Bryce Vickmark

This discovery sheds light on the chemical processes occurring in interstellar space, including gas-phase and surface reactions on dust grains, which are crucial for the evolution of organic chemistry. This further supports the notion that the primordial materials of our solar system contained a diverse range of organic compounds, providing insights into the potential for prebiotic chemistry on a young Earth and planetesimals.

Q: What specific challenges did you face in detecting pyrene, given that it is invisible to traditional radio astronomy methods, and how did the use of cyanopyrene help overcome these challenges?

Gabi Wenzel:

Pyrene, a fully symmetric PAH, does not possess a permanent electric dipole moment and hence is invisible in radio astronomical observations or rotational spectrometers in the laboratory. The CN radical is highly abundant in the cold and dark molecular cloud TMC-1, an environment that is about 10 K cold and in which you’d assume little chemistry to happen. However, earlier experimental works have shown that the CN addition (followed by hydrogen abstraction) to ringed hydrocarbon species such as benzene and toluene at low temperatures is a barrierless process.

Adding a CN (nitrile) group to a hydrocarbon will drastically increase its permanent electric dipole moment and so allow rotational transitions. Indeed, several CN-functionalized species have been detected in TMC-1 and other sources, among which the CN-substituted benzene (cyanobenzene or benzonitrile) and other smaller PAHs, with cyanopyrene being the largest molecule found via radio astronomy to date, allowing us to infer the presence of pyrene itself.

Q: Can you elaborate on what it means for our understanding of carbon sources in the solar system that pyrene is found in both TMC-1 and asteroid Ryugu?

Ilsa Cooke:

TMC-1 is a famous example of a cold molecular cloud, one of the earliest stages of star and planet formation, while asteroids like Ryugu represent snapshots of later stages in the formation of solar systems. Asteroids are formed from material in the solar nebula that was inherited from the molecular cloud stage. Our radio observations of TMC-1 let us observe pyrene early on and possibly under conditions where it is first forming. Isotope signatures of the pyrene in Ryugu suggest it was formed in a cold interstellar cloud. From these two unique sets of measurements, we can start to unravel the inheritance of pyrene, and PAHs more generally, from their birth in interstellar space and their journey to new planets. If PAHs can survive all the way from the molecular cloud stage, they may provide planets with an important source of organic carbon.

Dr. Cooke stands in front of the Green Bank Telescope. Credit Dr. Brett McGuire

Q: What are the different formation routes of PAHs that your research suggests, and how do these differ from previous hypotheses about PAH formation in space?

Ilsa Cooke:

Our results, combined with those of Zeichner et al., who measured pyrene in Ryugu, suggest that pyrene may form at low temperatures by “bottom-up” routes in molecular clouds. Previously, PAHs were most commonly associated with formation in high-temperature (ca. 1000 K) environments in the envelopes of dying stars. These stars are thought to eject their PAHs, along with other carbon-rich molecules, into the diffuse interstellar medium.

However, the diffuse medium is a tenuous, harsh environment permeated by ultraviolet photons, and most astrochemists think that small PAHs would not survive their journey through the diffuse medium into dense molecular clouds. So we are still left with a puzzle: does that pyrene that we observe in TMC-1 form there, or was it formed somewhere else but it was able to survive its journey more efficiently than previously thought? If the pyrene is indeed formed within TMC-1, we do not yet know the chemical mechanism. Many possibilities exist, so close collaborations between laboratory astrochemists and observers will be critical to answer this question.

The structure of Pyrene, a polycyclic aromatic hydrocarbon, or PAH. Credit: Wikimedia

Q: What are your plans for investigating larger PAH molecules in TMC-1, and what specific hypotheses are you looking to test with these investigations?

Brett McGuire:

We have a number of other targets lined up – again focusing on PAH structures that should show this special stability demonstrated by pyrene. They present the same experimental challenges, including needing to devise appropriate synthetic routes in the laboratory before collecting their spectra. The major question is just how complex the PAH inventory actually gets at this earliest stage of star formation.

Ball-and-stick model of the pyrene molecule, a polycyclic aromatic hydrocarbon consisting offour fused benzene rings. Credit: Wikimedia

Prior to our work in TMC-1, nearly everything we knew about PAHs came from infrared observations of bulk properties in much warmer and more energetic regions, where PAHs are thought to be much larger. Does the population in TMC-1 look the same as in these regions? Is it at an earlier stage of chemical evolution? And how does this distribution compare to what we see in our own Solar System?

Q: How do your findings about pyrene and PAHs in interstellar clouds influence our broader understanding of organic chemistry in the universe, particularly in relation to the origins of life?

Brett McGuire:

Life as we know it depends on carbon – it is the backbone upon which all our molecular structures are constructed. Yet, the Earth overall is somewhat depleted in carbon relative to what we’d naively expect, and we still don’t fully understand where the carbon we do have came from originally. PAHs in general seem to be a massive reservoir of reactive carbon, and what we are now seeing is that that reservoir is already present at the earliest stages of star-formation. Combined with the evidence from Ryugu, we’re now also seeing indications that the inventory of PAHs, and thus this reservoir of carbon, may actually survive from this dark molecular cloud phase through the formation of a star to be eventually incorporated into the planetary system itself.

Dipin is the Co-founder and Editor-in-Chief of EdPublica. A journalist and editor with over 15 years of experience leading and co-founding both print and digital media outlets, he has written extensively on education, politics, and culture. His work has appeared in global publications such as The Huffington Post, The Himalayan Times, DailyO, Education Insider, and others.

Space & Physics

Could Alien Life Thrive in Liquid That’s Not Water? MIT Scientists Propose a Dramatic New Possibility

A special blend of chemicals—known as ionic liquids—can easily form on rocky planets and moons, potentially creating new havens for life in the cosmos

Published

on

Illustrated image

For centuries, the search for life beyond Earth has been soaked in one belief: water is essential. Now, MIT researchers are challenging this planetary doctrine—suggesting that the ingredients for life could thrive in liquids far different from water, and perhaps on worlds much harsher than our own.

In a study published this week in Proceedings of the National Academy of Sciences, the MIT-led team demonstrated that a special blend of chemicals—known as ionic liquids—can easily form on rocky planets and moons, potentially creating new havens for life in the cosmos.

Ionic liquids are a type of salt that stays liquid at temperatures below 100°C and, unlike water, can endure extremes of heat and pressure. In their experiments, the researchers mixed sulfuric acid (often produced by volcanoes) with simple nitrogen-rich organic compounds (found on asteroids and planetary atmospheres). The result: a persistent, stable liquid that doesn’t evaporate even when most of the acid is gone.

Ionic liquids, it turns out, can be friendly to rare biomolecules—like hardy proteins—that can resist breakdown in harsh conditions.

Expanding the habitability zone

“We consider water to be required for life because that is what’s needed for Earth life. But if we look at a more general definition, we see that what we need is a liquid in which metabolism for life can take place,” said Dr. Rachana Agrawal, who led the study at MIT’s Department of Earth, Atmospheric and Planetary Sciences. “Now if we include ionic liquid as a possibility, this can dramatically increase the habitability zone for all rocky worlds.”

The implications are staggering: even on planets that are too hot, or whose atmospheres are too thin for water to exist, stable ionic liquids could form and persist—potentially nurturing forms of alien life, though they may look nothing like Earth’s water-based organisms.

From Venus to beyond

The inspiration came when the team was working to solve a Venus mystery. Venus, shrouded in clouds of sulfuric acid, has long fascinated scientists seeking signs of life. When Dr. Agrawal and her colleagues tried to evaporate sulfuric acid from a solution to isolate organic molecules, a stubborn liquid layer wouldn’t go away. They realized they’d accidentally created an ionic liquid—a discovery that opened new doors in astrobiology.

Dr. Sara Seager, MIT’s Class of 1941 Professor of Planetary Sciences and co-leader of the study, described the breakthrough: “In high school, you learn that an acid wants to donate a proton. Oddly enough, we knew from our past work that sulfuric acid (the main component of Venus’ clouds) and nitrogen-containing compounds have this unique chemistry—one gives up a hydrogen, one takes it. It’s like one person’s trash is another person’s treasure.”

After testing over 30 nitrogen compounds with sulfuric acid, the scientists confirmed that ionic liquids reliably form under a wide range of conditions—even on basalt rocks similar to those on planetary surfaces.

“We were just astonished that the ionic liquid forms under so many different conditions,” Seager said. “If you put the sulfuric acid and the organic on a rock, the excess acid seeps into the pores, but you’re still left with a drop of ionic liquid. Whatever we tried, ionic liquid still formed.”

Their experiments showed that this process happens up to 180°C and at pressures far below Earth’s, broadening the realm of possible habitable worlds.

New oases in the universe

Imagine a rocky world, hotter than Earth, where volcanic sulfuric acid flows over pockets of organic matter—ingredients for life scattered across the solar system. According to Dr. Seager, these spots could become long-lived pools of ionic liquid, tiny oases for simple, exotic life forms.

“We’re envisioning a planet warmer than Earth, that doesn’t have water, and at some point in its past or currently, it has to have had sulfuric acid, formed from volcanic outgassing,” Seager explained. “This sulfuric acid has to flow over a little pocket of organics. And organic deposits are extremely common in the solar system.”

Just how far could this discovery go? The team says much more work lies ahead. They will now focus on what kinds of molecules—and what forms of life—could actually flourish in these unearthly environments.

“We just opened up a Pandora’s box of new research,” Seager said. “It’s been a real journey.”

Contributors to the study include: MIT scientists Sara Seager, Rachana Agrawal, Iaroslav Iakubivskyi, Weston Buchanan, Ana Glidden, Jingcheng Huang; Maxwell Seager (Worcester Polytechnic Institute); William Bains (Cardiff University); Janusz Petkowski (Wroclaw University of Science and Technology).

Continue Reading

Space & Physics

Joint NASA-ISRO radar satellite is the most powerful built to date

NISAR – a portmanteau for the NASA-ISRO synthetic aperture global radar earth observation satellite — will only be the latest collaboration between the two space agencies.

Karthik Vinod

Published

on

A concept art on NISAR | Photo Credit: NASA

On July 30th, NISAR  — the NASA-ISRO joint space mission — launched to space aboard the GSLV Mark II rocket from Sriharikota, Andhra Pradesh. The satellite, now safely tucked into a sun-synchronous orbit around earth, will enter a commissioning phase over the next three months, to deploy all its instruments.

Perched at an altitude of 750 km, the three ton satellite will complete an orbit around the earth every 12 days, while studying the planet’s diverse geology with unprecedented detail.

NISAR, a portmanteau for the NASA-ISRO synthetic aperture radar mission, marks the culmination of a decade-long effort to build the most powerful earth observation satellite to date.

In 2007, NASA had begun actively exploring an ambitious undertaking to build a satellite, which could map the earth and the whole ecosystem. On the agenda were investigations into studying climate change and its role in exacerbating extreme weather events. These include surveillance over vulnerable hotspots, such as Greenland and Antarctica, where disappearing ice sheets have been linked to the global average increase in sea-levels over the years.

Remote sensing satellites traditionally used can’t capture the full picture, without uninterrupted sunlight exposure or obstructions namely cloud cover. But synthetic aperture radar is a fix to these problems. Clouds are transparent to radio and microwaves unlike visible light. As such, a synthetic aperture radar can work across any weather, whether sunlit or not alike.

That said, SAR technology isn’t new. They have been around for about seventy years, since the first proof of principle was proven in the 1950s. In 1978, the US launched the first SAR-equipped earth observation satellite, Seasat, to monitor oceans. Neither Seasat or for that matter any SAR-based successors, could bear resolutions as high as 1 cm, or map terrain across a swath area as wide as about 240 km, as NISAR can.

NASA engaged in a cost-effective strategy, opening doors for international partners to pool resources, and co-develop the satellite and the scientific campaigns.

A

B

(A) Melt pond in Greenland | Photo Credit: Michael Studinger (2008) (B) NASA administrator Charles Bolden and ISRO chairman K. Radhakrishnan sign documents, which included a charter on NISAR, in Toronto | Photo Credit: NASA (2014)

NASA and ISRO share expertise

NASA found an interested party in ISRO, which at the time was developing the Radar Imaging Satellite (RISAT), which had a smaller scope to study India’s geology. India, being especially vulnerable to floods, landslides and cyclones, couldn’t overlook the incentives an extra eye in the sky could provide.

NISAR can track and relay even the minutest of changes on the surface in near real-time. In principle, the satellite should detect a flooded area hidden from view to rescuers on-ground, or even traditional remote sensing satellites which use passive receivers. The satellite can serve a key role in an integrated multi-hazard early warning system.

In 2014, ISRO inked the NISAR agreement with NASA. The mission would only be their latest collaboration between the two space agencies. Previously, they had collaborated on 2008’s Chandrayaan-1. Back then, NASA’s Moon Mineralogy Mapper (M3) instrument and miniSAR radar onboard the Chandrayaan orbiter, led the famous detection of water ice on the moon. 

Although NISAR was originally slated for launch in 2020, innumerable delays followed as they sorted technical challenges, and the abrupt global lockdown amid COVID pandemic.

Upon project completion last year, NISAR had become the most expensive satellite built, with NASA and ISRO pouring some $1.5 billion into development. The costs were unevenly split between them; with NASA spending some $1.3 billion, and ISRO bearing a modest amount at $91 million.

But a white paper details ISRO had contributed an equal value in engineering various components, re-establishing parity. ISRO engineered the spacecraft body, readied tracking stations on-ground, and developed the short wavelength S-band radar. The S-band (at 12 cm) complements NASA’s longer wavelength L-band (24 cm) radar.

The L-band can track changes under thick foliage or leaves, under forests. It can even measure land deformation rates as tiny as 4 mm/year. While the L-band serves as NISAR’s primary means of acquiring radar data, ISRO’s S-band radar will help provide details that concern Indian earth scientists, monitoring coastal erosion for example. Both radars work in tandem with NASA-designed radar receiver and reflector – a 12-meter wide meshed net, resembling a canopy attached to the spacecraft body via a boom. 

Three months from now, once the commissioning phase is complete, NISAR will begin its observational runs, and beam radar data back to earth continuously. The National Remote Sensing Centre in Hyderabad, and Goddard Space Flight Centre in Maryland, will process the respective L & S-band data independently, and archive them online for the world to see, all in a matter of few hours.

Continue Reading

Space & Physics

New double-slit experiment proves Einstein’s predictions were off the mark

Results from an idealized version of the Young double-slit experiment has upheld key predictions from quantum theory.

Published

on

Two individual atoms suspended in a vacuum chamber are illuminated by a laser beam, serving as the two slits. Scattered light interference is captured by a highly sensitive camera shown as a screen. Credit: Courtesy of the researchers/MIT
  • MIT physicists perform the most idealized double-slit experiment to date, using individual atoms as slits.
  • Experiment confirms the quantum duality of light: light behaves as both a particle and a wave, but both behaviors can’t be observed simultaneously.
  • Findings disprove Albert Einstein’s century-old prediction regarding detecting a photon’s path alongside its wave nature.

In a study published in Physical Reviews Letters on July 22, researchers at MIT have realized an idealized version of the famous double-slit experiment in quantum physics yet.

The double-slit experiment—first devised in 1801 by the British physicist Thomas Young—remains a perplexing aspect of reality. Light waves passing through two slits, form interference patterns on a wall placed behind. But this phenomenon is at odds with the fact light also behaves as particles. The contradiction has lent itself to a paradox, which sits at the foundation of quantum mechanics. It has sparked a historic scientific duel nearly a century ago, between physics heavyweights Albert Einstein and Niels Bohr. The study’s findings have now settled the decades-old debate, showing Einstein’s predictions were off the mark.

Einstein had suggested that by detecting the force exerted when a photon passes through a slit—a nudge akin to a bird brushing past a leaf—scientists could witness both light’s wave and particle properties at once. Bohr countered with the argument that observing a photon’s path would inevitably erase its wave-like interference pattern, a tenet since embraced by quantum theory.

The MIT team stripped the experiment to its purest quantum elements. Using arrays of ultracold atoms as their slits and weak light beams to ensure only one photon scattered per atom, they tuned the quantum states of each atom to control the information gained about a photon’s journey. Every increase in “which-path” information reduced the visibility of the light’s interference pattern, flawlessly matching quantum theory and further debunking Einstein’s proposal.

“Einstein and Bohr would have never thought that this is possible, to perform such an experiment with single atoms and single photons,” study senior author and Nobel laureate, Wolfgang Ketterle, stated in a press release. “What we have done is an idealized Gedanken (thought) experiment.”

In a particularly stunning twist, Ketterle’s group also disproved the necessity of a physical “spring”—a fixture in Einstein’s original analogy—by holding their atomic lattice not with springs, but with light. When they briefly released the atoms, effectively making the slits “float” in space, the same quantum results persisted. “In many descriptions, the springs play a major role. But we show, no, the springs do not matter here; what matters is only the fuzziness of the atoms,” commented MIT researcher Vitaly Fedoseev in a media statement. “Therefore, one has to use a more profound description, which uses quantum correlations between photons and atoms.”

The paper arrives as the world prepares for 2025’s International Year of Quantum Science and Technology — marking 100 years since the birth of quantum mechanics. Yoo Kyung Lee, a fellow co-author, noted in a media statement, “It’s a wonderful coincidence that we could help clarify this historic controversy in the same year we celebrate quantum physics.”

Continue Reading

Trending